Tandem Catalysis of an Aldol-'Click' Reaction System within a Molecular Hydrogel.
نویسندگان
چکیده
A heterogeneous supramolecular catalytic system for multicomponent aldol-'click' reactions is reported. The copper(I) metallohydrogel functionalized with a phenyltriazole fragment was able to catalyze the multicomponent reaction between phenylacetylene, p-nitrobenzaldehyde, and an azide containing a ketone moiety, obtaining the corresponding aldol products in good yields. A possible mechanistic pathway responsible for this unexpected catalytic behavior has been proposed.
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ورودعنوان ژورنال:
- Molecules
دوره 21 6 شماره
صفحات -
تاریخ انتشار 2016